ASTM D6733 Standard Test Method for Determination of Individual Components in Spark Ignition Engine Fuels by 50-Metre Capillary High Resolution Gas Chromatography
ASTM D6733用50米毛細管高分辨率氣相色譜法測定火花點火發動機燃料中各種成分的標準試驗方法
Knowledge of the individual component composition (speciation) of gasoline fuels and blending stocks is useful for refinery quality control and product specification. Process control and product specification compliance for many individual hydrocarbons may be determined through the use of this test method.
1. Scope
1.1 This test method covers the determination of individual hydrocarbon components of spark-ignition engine fuels with boiling ranges up to 225°C. Other light liquid hydrocarbon mixtures typically encountered in petroleum refining operations, such as, blending stocks (naphthas, reformates, alkylates, and so forth) may also be analyzed; however, statistical data was obtained only with blended spark-ignition engine fuels. The tables in Annex A1 enumerate the components reported. Component concentrations are determined in the range from 0.10 to 15 mass %. The procedure may be applicable to higher and lower concentrations for the individual components; however, the user must verify the accuracy if the procedures are used for components with concentrations outside the specified ranges.
1.2 This test method is applicable also to spark-ignition engine fuel blends containing oxygenated components. However, in this case, the oxygenate content must be determined by Test Methods D5599 or D4815.
1.3 Benzene co-elutes with 1-methylcyclopentene. Benzene content must be determined by Test Method D3606 or D5580.
1.4 Toluene co-elutes with 2,3,3-trimethylpentane. Toluene content must be determined by Test Method D3606 or D5580.
1.5 Although a majority of the individual hydrocarbons present are determined, some co-elution of compounds is encountered. If this procedure is utilized to estimate bulk hydrocarbon group-type composition (PONA) the user of such data should be cautioned that error may be encountered due to co-elution and a lack of identification of all components present. Samples containing significant amounts of naphthenic (for example, virgin naphthas) constituents above n-octane may reflect significant errors in PONA type groupings. Based on the interlaboratory cooperative study, this procedure is applicable to samples having concentrations of olefins less than 20 mass %. However, significant interfering coelution with the olefins above C7 is possible, particularly if blending components or their higher boiling cuts such as those derived from fluid catalytic cracking (FCC) are analyzed, and the total olefin content may not be accurate. Many of the olefins in spark ignition fuels are at a concentration below 0.10 %; they are not reported by this test method and may bias the total olefin results low.
1.5.1 Total olefins in the samples may be obtained or confirmed, or both, by Test Method D1319 (volume %) or other test methods, such as those based on multidimensional PONA type of instruments.
1.6 If water is or is suspected of being present, its concentration may be determined, if desired, by the use of Test Method D1744. Other compounds containing sulfur, nitrogen, and so forth, may also be present, and may co-elute with the hydrocarbons. If determination of these specific compounds is required, it is recommended that test methods for these specific materials be used, such as Test Method D5623 for sulfur compounds.
1.7 The values stated in SI units are to be regarded as the standard. The values given in parentheses are provided for information only.
1.8 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety and health practices and determine the applicability of regulatory limitations prior to use.
2. Referenced Documents (purchase separately)
ASTM Standards
D1319 Test Method for Hydrocarbon Types in Liquid Petroleum Products by Fluorescent Indicator Adsorption
D1744 Standard Test Method for Determination of Water in Liquid Petroleum Products by Karl Fischer Reagent
D3606 Test Method for Determination of Benzene and Toluene in Finished Motor and Aviation Gasoline by Gas Chromatography
D4057 Practice for Manual Sampling of Petroleum and Petroleum Products
D4420 Test Method for Determination of Aromatics in Finished Gasoline by Gas Chromatography
D4815 Test Method for Determination of MTBE, ETBE, TAME, DIPE, tertiary-Amyl Alcohol and C1 to C4 Alcohols in Gasoline by Gas Chromatography
D5580 Test Method for Determination of Benzene, Toluene, Ethylbenzene, p/m-Xylene, o-Xylene, C9 and Heavier Aromatics, and Total Aromatics in Finished Gasoline by Gas Chromatography
D5599 Test Method for Determination of Oxygenates in Gasoline by Gas Chromatography and Oxygen Selective Flame Ionization Detection
D5623 Test Method for Sulfur Compounds in Light Petroleum Liquids by Gas Chromatography and Sulfur Selective Detection
E355 Practice for Gas Chromatography Terms and Relationships
D1744 Standard Test Method for Determination of Water in Liquid Petroleum Products by Karl Fischer Reagent
D3606 Test Method for Determination of Benzene and Toluene in Finished Motor and Aviation Gasoline by Gas Chromatography
D4057 Practice for Manual Sampling of Petroleum and Petroleum Products
D4420 Test Method for Determination of Aromatics in Finished Gasoline by Gas Chromatography
D4815 Test Method for Determination of MTBE, ETBE, TAME, DIPE, tertiary-Amyl Alcohol and C1 to C4 Alcohols in Gasoline by Gas Chromatography
D5580 Test Method for Determination of Benzene, Toluene, Ethylbenzene, p/m-Xylene, o-Xylene, C9 and Heavier Aromatics, and Total Aromatics in Finished Gasoline by Gas Chromatography
D5599 Test Method for Determination of Oxygenates in Gasoline by Gas Chromatography and Oxygen Selective Flame Ionization Detection
D5623 Test Method for Sulfur Compounds in Light Petroleum Liquids by Gas Chromatography and Sulfur Selective Detection
E355 Practice for Gas Chromatography Terms and Relationships
Index Terms
detailed hydrocarbon analysis; DHA; gas chromatography; gasoline; hydrocarbons; open tubular; oxygenates; spark ignition engine fuels; Automotive engine fuels/oils; Column tests; Composition analysis--petroleum products; Detailed hydrocarbon analysis (DHA); Gas chromatography (GC)--petroleum products; High-resolution gas chromatography (GC); Hydrocarbons (aromatic); Open tubular column; Oxygenates; PONA (bulk hydrocarbon group-type composition); 
